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Haloalkanes and Haloarenes

RE-NEET (UG) 2024MCQEasy📈 Topic in 25% papers+4−1
Ques. 1RE-NEET (UG) 2024

The following reaction method [figure] is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :

  1. F
  2. I
  3. Cl
  4. Br

Answer

(1) F

Solution

Fluorine is so reactive that its reaction with arenes is violent and cannot be controlled, so aryl fluorides are not prepared by direct halogenation (they are made from diazonium salts by the Balz–Schiemann reaction).

(Iodination is reversible and needs an oxidising agent such as HNO3 or HIO4, but that is due to the low reactivity of iodine.)

Answer: (1)

Keep practising — Haloalkanes and Haloarenes

Ques. 2NEET (UG) 2023

The given compound [figure] is an example of .

  1. aryl halide
  2. allylic halide
  3. vinylic halide
  4. benzylic halide
Ques. 3NEET (UG) 2023

Identify the final product [D] obtained in the following sequence of reactions. [figure]

  1. [figure]
  2. C4H10
  3. HC C Na
  4. [figure]
Ques. 4NEET (UG) 2022

Which of the following sequence of reactions is suitable to synthesize chlorobenzene?

  1. Benzene, Cl2, anhydrous FeCl3
  2. Phenol, NaNO2, HCl, CuCl
  3. [figure] , HCl
  4. [figure] , HCl, Heating
Ques. 5NEET (UG) 2022 (Phase 2)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A) is not correct but (R) is correct
  2. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  3. Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  4. (A) is correct but (R) is not correct
Ques. 6NEET (UG) 2022 (Phase 2)

Predict the order of reactivity of the following four isomers towards SN2 reaction. (I) CH3CH2CH2CH2Cl (II) CH3CH2CH(Cl)CH3 (III) (CH3)2CHCH2Cl (IV) (CH3)3CCl

  1. (IV) > (II) > (III) > (I)
  2. (IV) > (III) > (II) > (I)
  3. (I) > (II) > (III) > (IV)
  4. (I) > (III) > (II) > (IV)
Ques. 7NEET (UG) 2021

The major product formed in dehydrohalogenation reaction of 2-bromopentane is pent-2-ene. This product formation is based on?

  1. Hückel's Rule
  2. Saytzeff's Rule
  3. Hund's Rule
  4. Hofmann Rule
Ques. 8NEET (UG) 2021

The correct sequence of bond enthalpy of 'C-X' bond is :

  1. CH3-Cl > CH3-F > CH3-Br > CH3-I
  2. CH3-F < CH3-Cl < CH3-Br < CH3-I
  3. CH3-F > CH3-Cl > CH3-Br > CH3-I
  4. CH3-F < CH3-Cl > CH3-Br > CH3-I
Ques. 9NEET (UG) 2020

Elimination reaction of 2-Bromopentane to form pent-2-ene is :

  1. A, C and D only
  2. B, C and D only
  3. A, B and D only
  4. A, B and C only
Ques. 10NEET 2018

The compound C7H8 undergoes the following reactions : C7H8 3Cl2/ A Br2/Fe B Zn/HCl C The product 'C' is

  1. m-bromotoluene
  2. o-bromotoluene
  3. 3-bromo-2,4,6-trichlorotoluene
  4. p-bromotoluene
Ques. 11NEET 2017

Identify A and predict the type of reaction. [figure]

  1. [figure] and elimination addition reaction
  2. [figure] and cine substitution reaction
  3. [figure] and cine substitution
  4. [figure] and substitution reaction

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