Coordination Compounds

Which of the following sequences of hybridisation, geometry and magnetic nature are correct for the given coordination compounds ? Choose the correct answer from the options given below :

1. A, B, C and D
2. B, C and D only
3. A, C and D only
4. A, B and D only

The correct statement among the following is:

1. [Ni(CN)4]2- and [NiCl4]2- are diamagnetic and Ni(CO)4 is paramagnetic.
2. Ni(CO)4 is diamagnetic and [NiCl4]2- and [Ni(CN)4]2- are paramagnetic.
3. Ni(CO)4 and [NiCl4]2- are diamagnetic and [Ni(CN)4]2- is paramagnetic.
4. Ni(CO)4 and [Ni(CN)4]2- are diamagnetic and [NiCl4]2- is paramagnetic.

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below

1. Both Statement I and Statement II are false
2. Statement I is true but Statement II is false
3. Both Statement I and Statement II are true
4. Statement I is false but Statement II is true

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

1. Statement I is true but Statement II is false
2. Both Statement I and Statement II are false
3. Statement I is false but Statement II is true
4. Both Statement I and Statement II are true

Identify the CORRECT set of details from the following : Choose the correct answer from the options given below :

1. C & D Only
2. A, C & E Only
3. A, B, C, D & E
4. A, B & D Only

Total number of unpaired electrons present in the central metal atoms/ions of [Ni(CO)4], [NiCl4]2-, [PtCl2(NH3)2], [Ni(CN)4]2- and [Pt(CN)4]2- is .

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is false but Statement II is true
2. Both Statement I and Statement II are false
3. Both Statement I and Statement II are true
4. Statement I is true but Statement II is false

Match the LIST-I with LIST-II Choose the correct answer from the options given below:

1. A-I, B-II, C-III, D-IV
2. A-IV, B-I, C-III, D-II
3. A-III, B-II, C-I, D-IV
4. A-III, B-IV, C-II, D-I

The number of species from the following that are involved in sp3d2 hybridization is : [Co(NH3)6]3+, SF6, [CrF6]3-, [CoF6]3-, [Mn(CN)6]3-, and [MnCl6]3-

1. 4
2. 3
3. 5
4. 6

The number of paramagnetic complexes among [FeF6]3-, [Fe(CN)6]3-, [Mn(CN)6]3-, [Co(C2O4)3]3-, [MnCl6]3-, and [CoF6]3-, which involve d2sp3 hybridization is .

The number of paramagnetic metal complex species among [Co(NH3)6]3+, [Co(C2O4)3]3-, [MnCl6]3-, [Mn(CN)6]3-, [CoF6]3-, [Fe(CN)6]3- and [FeF6]3- with same number of unpaired electrons is .

The correct order of [FeF6]3-, [CoF6]3-, [Ni(CO)4] and [Ni(CN)4]2- complex species based on the number of unpaired electrons present is:

1. [CoF6]3- > [FeF6]3- > [Ni(CO)4] > [Ni(CN)4]2-
2. [FeF6]3- > [CoF6]3- > [Ni(CN)4]2- > [Ni(CO)4]
3. [FeF6]3- > [CoF6]3- > [Ni(CN)4]2- = [Ni(CO)4]
4. [Ni(CN)4]2- > [FeF6]3- > [CoF6]3- > [Ni(CO)4]

Identify the diamagnetic octahedral complex ions from below ; Choose the correct answer from the options given below:

1. B and C Only
2. A and C Only
3. B and D Only
4. A and D Only

The type of hybridization and the magnetic property of [MnCl6]3- are,

1. sp3d2, paramagnetic with four unpaired electrons.
2. d2sp3, paramagnetic with four unpaired electrons.
3. sp3d2, paramagnetic with two unpaired electrons.
4. d2sp3, paramagnetic with two unpaired electrons.

Match List - I with List - II. Choose the correct answer from the options given below :

1. (A)-(III), (B)-(I), (C)-(I), (D)-(IV)
2. (A)-(III), (B)-(II), (C)-(III), (D)-(IV)
3. (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
4. (A)-(IV), (B)-(I), (C)-(II), (D)-(III)

Match List - I with List - II. Choose the correct answer from the options given below:

1. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
2. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
3. (A)-(I), (B)-(IV), (C)-(III), (D)-(II)
4. (A)-(III), (B)-(II), (C)-(I), (D)-(IV)

From the magnetic behaviour of [NiCl4]2- (paramagnetic) and [Ni(CO)4] (diamagnetic), choose the correct geometry and oxidation state.

1. [NiCl4]2- : Ni(0), tetrahedral [Ni(CO)4] : Ni(0), square planar
2. [NiCl4]2- : NiII, tetrahedral [Ni(CO)4] : Ni(0), tetrahedral
3. [NiCl4]2- : NiII, tetrahedral [Ni(CO)4] : NiII, square planar
4. [NiCl4]2- : NiII, square planar [Ni(CO)4] : Ni(0), square planar

Match List I with List II Choose the correct answer from the options given below:

1. A-III, B-II, C-IV, D-I
2. A-III, B-I, C-II, D-IV
3. A-I, B-III, C-II, D-IV
4. A-III, B-I, C-IV, D-II

[Co(NH3)6]3+ and [CoF6]3- are respectively known as :

1. Inner orbital Complex, Spin paired Complex
2. Spin paired Complex, Spin free Complex
3. Spin free Complex, Spin paired Complex
4. Outer orbital Complex, Inner orbital Complex

The correct statements from following are: Choose the correct answer from the options given below:

1. B, C only
2. B, D only
3. A, C only
4. A, D only

Select the option with correct property -

1. [Ni(CO)4] and [NiCl4]2- both Paramagnetic
2. [Ni(CO)4] and [NiCl4]2- both Diamagnetic
3. [NiCl4]2- Diamagnetic, [Ni(CO)4] Paramagnetic
4. [Ni(CO)4] Diamagnetic, [NiCl4]2- Paramagnetic

Identify from the following species in which d2sp3 hybridization is shown by central atom :

1. [Co(NH3)6]3+
2. SF6
3. [PtCl4]2-
4. BrF5

The Spin only magnetic moment value of square planar complex [Pt(NH3)2Cl(NH2CH3)]Cl is B.M. (Nearest integer) (Given atomic number for Pt = 78)