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Chemical Kinetics

Previous year questions with solutions · 2024 – 2026

73Questions
58Papers covered
5.68%Weightage 2026▲ 3.8% vs last year
’24
’25
’26
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202627191.45.68% ▲ 3.8% vs last year
202526191.45.47% ▲ 64.5% vs last year
202420210.953.33%

⚠ 1 of these questions are out of the current syllabus (marked on the question).

73 questions · newest paper first · page 3 of 3

Ques. 61JEE Main 2024, 5 April (Evening Shift)

Consider the following single step reaction in gas phase at constant temperature. 2A(g) + B(g) C(g) The initial rate of the reaction is recorded as r1 when the reaction starts with 1.5 atm pressure of A and 0.7 atm pressure of B. After some time, the rate r2 is recorded when the pressure of C becomes 0.5 atm. The ratio r1 : r2 is 10-1. (Nearest integer)

Ques. 62JEE Main 2024, 4 April (Morning Shift)

Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below. [figure] Some details of the above reactions are listed below. [figure] If the overall rate constant of the above transformation (k) is given as k = k1k2k3 and the overall activation energy (Ea) is 400 kJ mol-1, then the value of Ea3 is kJ mol-1 (nearest integer)

Ques. 63JEE Main 2024, 4 April (Evening Shift)

Consider the following reaction, the rate expression of which is given below A + B C rate = k[A]1/2[B]1/2 The reaction is initiated by taking 1 M concentration of A and B each. If the rate constant (k) is 4.6 10-2 s-1, then the time taken for A to become 0.1 M is sec. (nearest integer)

Ques. 64JEE Main 2024, 1 February (Morning Shift)

The ratio of 14C12C in a piece of wood is 18 part that of atmosphere. If half life of 14C is 5730 years, the age of wood sample is years.

Ques. 65JEE Main 2024, 1 February (Evening Shift)

The following data were obtained during the first order thermal decomposition of a gas A at constant volume : A(g) 2B(g) + C(g) [figure] The rate constant of the reaction is 10-2 s-1 (nearest integer)

Ques. 66JEE Main 2024, 31 January (Morning Shift)

Integrated rate law equation for a first order gas phase reaction is given by (where Pi is initial pressure and Pt is total pressure at time t)

  1. k = 2.303t Pi(2Pi - Pt)
  2. k = 2.303t (2Pi - Pt)Pi
  3. k = 2.303t Pi(2Pi - Pt)
  4. k = 2.303t 2Pi(2Pi - Pt)
Ques. 67JEE Main 2024, 31 January (Evening Shift)

r = k[A] for a reaction, 50% of A is decomposed in 120 minutes. The time taken for 90% decomposition of A is minutes.

Ques. 68JEE Main 2024, 30 January (Morning Shift)

The rate of a first order reaction is 0.04 mol L-1 s-1 at 10 minutes and 0.03 mol L-1 s-1 at 20 minutes after initiation. Half life of the reaction is minutes. (Given 2 = 0.3010, 3 = 0.4771)

Ques. 69JEE Main 2024, 30 January (Evening Shift)

NO2 required for a reaction is produced by decomposition of N2O5 in CCl4 as by equation 2N2O5(g) 4NO2(g) + O2(g) The initial concentration of N2O5 is 3 mol L-1 and it is 2.75 mol L-1 after 30 minutes. The rate of formation of NO2 is x 10-3 mol L-1 min-1, value of x is . (nearest integer)

Ques. 70JEE Main 2024, 29 January (Morning Shift)

For a reaction taking place in three steps at same temperature, overall rate constant K = K1 K2K3. If Ea1, Ea2 and Ea3 are 40, 50 and 60 kJ/mol respectively, the overall Ea is kJ/mol.

Ques. 71JEE Main 2024, 29 January (Evening Shift)

The half-life of radioisotope bromine - 82 is 36 hours. The fraction which remains after one day is 10-2. (Given antilog 0.2006 = 1.587)

Ques. 72JEE Main 2024, 27 January (Morning Shift)

Consider the following data for the given reaction 2HI(g) H2(g) + I2(g) [figure] The order of the reaction is .

Ques. 73JEE Main 2024, 27 January (Evening Shift)

Time required for completion of 99.9% of a First order reaction is times of half life (t1/2) of the reaction.