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Chemical Bonding and Molecular Structure

Previous year questions with solutions · 2024 – 2026

85Questions
56Papers covered
4.63%Weightage 2026▲ 10% vs last year
’24
’25
’26
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202622191.24.63% ▲ 10% vs last year
202520191.14.21% ▼ 41.2% vs last year
2024432127.15%

26 questions · newest paper first

Ques. 1JEE Main 2026, 5 April (Morning Shift)

Consider the following species: BrF5, XeF5-, BF4-, ICl4-, XeF4, SF4, NH4+, ClF3, XeF2, ICl2- Number of species having sp3d hybridized central atom is .

Ques. 2JEE Main 2026, 4 April (Morning Shift)

According to Lewis theory, the total number of bond-pairs and lone pair of electrons around the central atom of XeO64- ion is .

Ques. 3JEE Main 2025, 29 January (Morning Shift)

The sum of sigma ( ) and pi ( ) bonds in Hex-1,3-dien-5-yne is .

Ques. 4JEE Main 2025, 29 January (Evening Shift)

Total number of non-bonded electrons present in NO2- ion based on Lewis theory is .

Ques. 5JEE Main 2025, 28 January (Evening Shift)

Total number of molecules/species from the following which will be paramagnetic is . O2, O2+, O2-, NO, NO2, CO, K2[NiCl4], [Co(NH3)6]Cl3, K2[Ni(CN)4]

Ques. 6JEE Main 2025, 22 January (Morning Shift)

The number of molecules/ions that show linear geometry among the following is . SO2, BeCl2, CO2, N3-, NO2, F2O, XeF2, NO2+, I3-, O3

Ques. 7JEE Main 2024, 9 April (Morning Shift)

The total number of species from the following in which one unpaired electron is present, is . N2, O2, C2-, O2-, O22-, H2+, CN-, He2+

Ques. 8JEE Main 2024, 9 April (Evening Shift)

Total number of electrons present in ( ) molecular orbitals of O2, O2+ and O2- is .

Ques. 9JEE Main 2024, 8 April (Morning Shift)

Number of molecules from the following which are exceptions to octet rule is . CO2, NO2, H2SO4, BF3, CH4, SiF4, ClO2, PCl5, BeF2, C2H6, CHCl3, CBr4

Ques. 10JEE Main 2024, 8 April (Evening Shift)

Number of molecules having bond order 2 from the following molecules is . C2, O2, Be2, Li2, Ne2, N2, He2

Ques. 11JEE Main 2024, 6 April (Morning Shift)

Number of molecules from the following which can exhibit hydrogen bonding is . (nearest integer) CH3OH, H2O, C2H6, C6H6, [figure] , HF, NH3

Ques. 12JEE Main 2024, 6 April (Evening Shift)

Total number of species from the following with central atom utilising sp2 hybrid orbitals for bonding is . NH3, SO2, SiO2, BeCl2, C2H2, C2H4, BCl3, HCHO, C6H6, BF3, C2H4Cl2

Ques. 13JEE Main 2024, 5 April (Morning Shift)

In the Lewis dot structure for NO2-, total number of valence electrons around nitrogen is .

Ques. 14JEE Main 2024, 5 April (Evening Shift)

Number of compounds from the following with zero dipole moment is . HF, H2, H2S, CO2, NH3, BF3, CH4, CHCl3, SiF4, H2O, BeF2

Ques. 15JEE Main 2024, 4 April (Morning Shift)

Number of molecules/species from the following having one unpaired electron is . O2, O2-1, NO, CN-1, O22-

Ques. 16JEE Main 2024, 4 April (Evening Shift)

Number of compounds / species from the following with non-zero dipole moment is . BeCl2, BCl3, NF3, XeF4, CCl4, H2O, H2S, HBr, CO2, H2, HCl

Ques. 17JEE Main 2024, 1 February (Morning Shift)

The number of molecules/ion/s having trigonal bipyramidal shape is . PF5, BrF5, PCl5, [PtCl4]2-, BF3, Fe(CO)5

Ques. 18JEE Main 2024, 31 January (Morning Shift)

The number of species from the following in which the central atom uses sp3 hybrid orbitals in its bonding is . NH3, SO2, SiO2, BeCl2, CO2, H2O, CH4, BF3

Ques. 19JEE Main 2024, 31 January (Evening Shift)

A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1 Å, then fractional charge on each atom is 10-1 esu. (Given 1 D = 10-18 esucm)

Ques. 20JEE Main 2024, 30 January (Morning Shift)

The total number of molecular orbitals formed from 2s and 2p atomic orbitals of a diatomic molecule is .

Ques. 21JEE Main 2024, 29 January (Morning Shift)

The number of species from the following which are paramagnetic and with bond order equal to one is . H2, He2+, O2+, N22-, O22-, F2, Ne2+, B2

Ques. 22JEE Main 2024, 29 January (Morning Shift)

Number of compounds with one lone pair of electrons on central atom amongst following is . O3, H2O, SF4, ClF3, NH3, BrF5, XeF4

Ques. 23JEE Main 2024, 29 January (Evening Shift)

The total number of molecules with zero dipole moment among CH4, BF3, H2O, HF, NH3, CO2 and SO2 is .

Ques. 24JEE Main 2024, 29 January (Evening Shift)

The total number of anti bonding molecular orbitals, formed from 2s and 2p atomic orbitals in a diatomic molecule is .

Ques. 25JEE Main 2024, 27 January (Morning Shift)

Sum of bond order of CO and NO+ is .

Ques. 26JEE Main 2024, 27 January (Evening Shift)

The number of non-polar molecules from the following is . HF, H2O, SO2, H2, CO2, CH4, NH3, HCl, CHCl3, BF3