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Chemical Bonding and Molecular Structure

Previous year questions with solutions · 2024 – 2026

85Questions
56Papers covered
4.63%Weightage 2026▲ 10% vs last year
’24
’25
’26
Year-wise statistics questions · papers · average per paper · weightage
YearQuestionsPapersAvg / paperWeightage
202622191.24.63% ▲ 10% vs last year
202520191.14.21% ▼ 41.2% vs last year
2024432127.15%

49 questions · newest paper first · page 2 of 2

Ques. 31JEE Main 2025, 24 January (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Statement I is false but Statement II is true
  2. Both Statement I and Statement II are true
  3. Statement I is true but Statement II is false
  4. Both Statement I and Statement II are false
Ques. 32JEE Main 2025, 22 January (Evening Shift)

Arrange the following compounds in increasing order of their dipole moment : HBr, H2S, NF3 and CHCl3

  1. HBr < H2S < NF3 < CHCl3
  2. H2S < HBr < NF3 < CHCl3
  3. NF3 < HBr < H2S < CHCl3
  4. CHCl3 < NF3 < HBr < H2S
Ques. 33JEE Main 2024, 9 April (Morning Shift)

In which one of the following pairs the central atoms exhibit sp2 hybridization ?

  1. BF3 and NO2-
  2. NH2- and BF3
  3. NH2- and H2O
  4. H2O and NO2
Ques. 34JEE Main 2024, 9 April (Evening Shift)

The correct increasing order for bond angles among BF3, PF3 and ClF3 is :

  1. BF3 = PF3 < ClF3
  2. BF3 < PF3 < ClF3
  3. ClF3 < PF3 < BF3
  4. PF3 < BF3 < ClF3
Ques. 35JEE Main 2024, 8 April (Evening Shift)

When A and B are the wave functions of atomic orbitals, then is represented by :

  1. A + 2 B
  2. A - B
  3. A - 2 B
  4. A + B
Ques. 36JEE Main 2024, 6 April (Evening Shift)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are false
  2. Statement I is true but Statement II is false
  3. Statement I is false but Statement II is true
  4. Both Statement I and Statement II are true
Ques. 37JEE Main 2024, 5 April (Evening Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the correct answer from the options given below :

  1. (A) is false but (R) is true
  2. (A) is true but (R) is false
  3. Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
  4. Both (A) and (R) are true and (R) is the correct explanation of (A)
Ques. 38JEE Main 2024, 4 April (Morning Shift)

Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is . NO3-, BCl3, ClO2-, ClO3-

  1. 2
  2. 4
  3. 1
  4. 3
Ques. 39JEE Main 2024, 4 April (Morning Shift)

Which one of the following molecules has maximum dipole moment?

  1. CH4
  2. NF3
  3. NH3
  4. PF5
Ques. 40JEE Main 2024, 4 April (Evening Shift)

The correct statement/s about Hydrogen bonding is/are Choose the correct answer from the options given below:

  1. A, B, C only
  2. A only
  3. A, D, E only
  4. A, B, D only
Ques. 41JEE Main 2024, 4 April (Evening Shift)

The number of species from the following that have pyramidal geometry around the central atom is S2O32-, SO42-, SO32-, S2O72-

  1. 4
  2. 3
  3. 2
  4. 1
Ques. 42JEE Main 2024, 1 February (Morning Shift)

Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O, N2, SO2 and ClF3 :

  1. N2 < SO2 < ClF3 < K2O < LiF
  2. ClF3 < N2 < SO2 < K2O < LiF
  3. LiF < K2O < ClF3 < SO2 < N2
  4. N2 < ClF3 < SO2 < K2O < LiF
Ques. 43JEE Main 2024, 1 February (Evening Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
Ques. 44JEE Main 2024, 1 February (Evening Shift)

Select the compound from the following that will show intramolecular hydrogen bonding.

  1. [figure]
  2. H2O
  3. C2H5OH
  4. NH3
Ques. 45JEE Main 2024, 31 January (Morning Shift)

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals Choose the most appropriate from the options given below:

  1. B, C, D only
  2. A, B, C only
  3. B and D only
  4. A and C only
Ques. 46JEE Main 2024, 31 January (Evening Shift)

Which of the following is least ionic?

  1. CoCl2
  2. KCl
  3. BaCl2
  4. AgCl
Ques. 47JEE Main 2024, 30 January (Evening Shift)

Given below are two statements: In the light of the above statements, choose the most appropriate from the options given below:

  1. Statement I is true but Statement II is false.
  2. Both Statement I and Statement II are true.
  3. Both Statement I and Statement II are false.
  4. Statement I is false but Statement II is true.
Ques. 48JEE Main 2024, 30 January (Evening Shift)

The molecule / ion with square pyramidal shape is

  1. PCl5
  2. [Ni(CN)4]2-
  3. PF5
  4. BrF5
Ques. 49JEE Main 2024, 27 January (Morning Shift)

Choose the polar molecule from the following:

  1. CCl4
  2. CO2
  3. CH2=CH2
  4. CHCl3