Chemical Bonding and Molecular Structure
Previous year questions with solutions · 2024 – 2026
85 Questions
56 Papers covered
4.63% Weightage 2026 ▲ 10% vs last year
Year-wise statistics questions · papers · average per paper · weightage Year Questions Papers Avg / paper Weightage 2026 22 19 1.2 4.63% ▲ 10% vs last year 2025 20 19 1.1 4.21% ▼ 41.2% vs last year 2024 43 21 2 7.15%
All 85 MCQ 49 Matching 10 Numerical 26
Topic All topics Bond Parameters: Bond Length, Bond Energy and Bond Angle Dipole Moment, Polarity and Non-Polar Molecules Fajans' Rule Formal Charge and Resonance Hybridisation Hydrogen Bonding and van der Waals Forces Ionic Bond and Kossel–Lewis Theory Lewis Structures, Octet Rule and Coordinate Bond Molecular Orbital Theory (MOT) VSEPR Theory and Molecular Geometry Valence Bond Theory (VBT) and Orbital Overlap Year All years 2026 2025 2024
Ques. 31 JEE Main 2025, 24 January (Evening Shift)
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
Statement I is false but Statement II is true Both Statement I and Statement II are true Statement I is true but Statement II is false Both Statement I and Statement II are false
Ques. 32 JEE Main 2025, 22 January (Evening Shift)
Arrange the following compounds in increasing order of their dipole moment : HBr, H2S, NF3 and CHCl3
HBr < H2S < NF3 < CHCl3 H2S < HBr < NF3 < CHCl3 NF3 < HBr < H2S < CHCl3 CHCl3 < NF3 < HBr < H2S
Ques. 33 JEE Main 2024, 9 April (Morning Shift)
In which one of the following pairs the central atoms exhibit sp2 hybridization ?
BF3 and NO2- NH2- and BF3 NH2- and H2O H2O and NO2
Ques. 34 JEE Main 2024, 9 April (Evening Shift)
The correct increasing order for bond angles among BF3, PF3 and ClF3 is :
BF3 = PF3 < ClF3 BF3 < PF3 < ClF3 ClF3 < PF3 < BF3 PF3 < BF3 < ClF3
Ques. 35 JEE Main 2024, 8 April (Evening Shift)
When A and B are the wave functions of atomic orbitals, then is represented by :
A + 2 B A - B A - 2 B A + B
Ques. 36 JEE Main 2024, 6 April (Evening Shift)
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true Both Statement I and Statement II are true
Ques. 37 JEE Main 2024, 5 April (Evening Shift)
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the correct answer from the options given below :
(A) is false but (R) is true (A) is true but (R) is false Both (A) and (R) are true but (R) is NOT the correct explanation of (A) Both (A) and (R) are true and (R) is the correct explanation of (A)
Ques. 38 JEE Main 2024, 4 April (Morning Shift)
Number of molecules/ions from the following in which the central atom is involved in sp3 hybridization is . NO3-, BCl3, ClO2-, ClO3-
2 4 1 3
Ques. 39 JEE Main 2024, 4 April (Morning Shift)
Which one of the following molecules has maximum dipole moment?
CH4 NF3 NH3 PF5
Ques. 40 JEE Main 2024, 4 April (Evening Shift)
The correct statement/s about Hydrogen bonding is/are Choose the correct answer from the options given below:
A, B, C only A only A, D, E only A, B, D only
Ques. 41 JEE Main 2024, 4 April (Evening Shift)
The number of species from the following that have pyramidal geometry around the central atom is S2O32-, SO42-, SO32-, S2O72-
4 3 2 1
Ques. 42 JEE Main 2024, 1 February (Morning Shift)
Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O, N2, SO2 and ClF3 :
N2 < SO2 < ClF3 < K2O < LiF ClF3 < N2 < SO2 < K2O < LiF LiF < K2O < ClF3 < SO2 < N2 N2 < ClF3 < SO2 < K2O < LiF
Ques. 43 JEE Main 2024, 1 February (Evening Shift)
Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :
Both Statement I and Statement II are true Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true
Ques. 44 JEE Main 2024, 1 February (Evening Shift)
Select the compound from the following that will show intramolecular hydrogen bonding.
[figure] H2O C2H5OH NH3
Ques. 45 JEE Main 2024, 31 January (Morning Shift)
The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals Choose the most appropriate from the options given below:
B, C, D only A, B, C only B and D only A and C only
Ques. 46 JEE Main 2024, 31 January (Evening Shift)
Which of the following is least ionic?
CoCl2 KCl BaCl2 AgCl
Ques. 47 JEE Main 2024, 30 January (Evening Shift)
Given below are two statements: In the light of the above statements, choose the most appropriate from the options given below:
Statement I is true but Statement II is false. Both Statement I and Statement II are true. Both Statement I and Statement II are false. Statement I is false but Statement II is true.
Ques. 48 JEE Main 2024, 30 January (Evening Shift)
The molecule / ion with square pyramidal shape is
PCl5 [Ni(CN)4]2- PF5 BrF5
Ques. 49 JEE Main 2024, 27 January (Morning Shift)
Choose the polar molecule from the following:
CCl4 CO2 CH2=CH2 CHCl3