'x' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. 'y' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous AlCl3. Product (major) obtained by heating x and y in the presence of alkali is z. Total number of π (pi) electrons in z is .
Aldehydes, Ketones and Carboxylic Acids
Previous year questions with solutions · 2024 – 2026
Year-wise statistics questions · papers · average per paper · weightage
| Year | Questions | Papers | Avg / paper | Weightage |
|---|---|---|---|---|
| 2026 | 24 | 19 | 1.3 | 5.05% same as last year |
| 2025 | 24 | 19 | 1.3 | 5.05% ▼ 13.2% vs last year |
| 2024 | 35 | 21 | 1.7 | 5.82% |
Consider the following sequence of reactions to give the major product (X) [figure] P g of the major product (X) formed is reacted with NaHCO3 solution to liberate a gas which occupied 11.2 dm3 at STP. P = g. (Given molar mass in g mol-1 H : 1, C : 12, O : 16, Cl : 35.5)
Grignard reagent RMgBr (P) reacts with water and forms a gas (Q). One gram of Q occupies 1.4 dm3 at STP. (P) on reaction with dry ice in dry ether followed by H3O+ forms a compound (Z). 0.1 mole of (Z) will weigh g. (Nearest integer)
Consider the following reaction of benzene. [figure] In compound (Q), the percentage of oxygen is %. (Nearest integer)
[figure] 0.1 mole of compound 'S' will weigh g. (Given molar mass in g mol-1 C : 12, H : 1, O : 16)
In the Claisen-Schmidt reaction to prepare dibenzalacetone from 5.3 g of benzaldehyde, a total of 3.51 g of product was obtained. The percentage yield in this reaction was %.
Major product B of the following reaction has -bond. [figure]
Two moles of benzaldehyde and one mole of acetone under alkaline conditions using aqueous NaOH after heating gives x as the major product. The number of bonds in the product x is .
The product C in the following sequence of reactions has bonds. [figure]
In the Claisen-Schmidt reaction to prepare 351 g of dibenzalacetone using 87 g of acetone, the amount of benzaldehyde required is g. (Nearest integer)
The number of the correct reaction(s) among the following is . [figure]
The product of the following reaction is P. [figure] The number of hydroxyl groups present in the product P is .
The compound formed by the reaction of ethanal with semicarbazide contains number of nitrogen atoms.
From the compounds given below, number of compounds which give positive Fehling's test is . Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4-nitrobenzaldehyde, cyclohexane carbaldehyde.