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Aldehydes, Ketones and Carboxylic Acids

NEET (UG) 2024MCQMedium📈 Topic in 50% papers+4−1
Ques. 1NEET (UG) 2024

Identify the correct reagents that would bring about the following transformation. [figure]

  1. (i) H2O/H+, (ii) CrO3
  2. (i) BH3, (ii) H2O2/OH , (iii) PCC
  3. (i) BH3, (ii) H2O2/OH , (iii) alk. KMnO4
  4. (i) H2O/H+, (ii) PCC

Answer

(2) (i) BH3, (ii) H2O2/OH , (iii) PCC

Solution

The product is an aldehyde with the C=O at the terminal carbon, so water must add in the anti-Markovnikov way and the primary alcohol must then be oxidised only up to the aldehyde.

(i) BH3, (ii) H2O2/OH (hydroboration–oxidation): C6H11CH2CH=CH2 C6H11CH2CH2CH2OH

(iii) PCC oxidises the 1 alcohol to the aldehyde: C6H11CH2CH2CH2OH C6H11CH2CH2CHO

H2O/H+ (Markovnikov) would give a 2 alcohol and hence a ketone; alk. KMnO4 would oxidise further to the acid.

Answer: (2)

Keep practising — Aldehydes, Ketones and Carboxylic Acids

Ques. 2NEET (UG) 2024

Fehling's solution 'A' is

  1. aqueous copper sulphate
  2. alkaline copper sulphate
  3. alkaline solution of sodium potassium tartrate (Rochelle's salt)
  4. aqueous sodium citrate
Ques. 3NEET (UG) 2024

Match List I with List II. Choose the correct answer from the options given below:

  1. A-IV, B-I, C-III, D-II
  2. A-III, B-I, C-II, D-IV
  3. A-IV, B-I, C-II, D-III
  4. A-I, B-IV, C-II, D-III
Ques. 4RE-NEET (UG) 2024

Select the incorrect reaction among the following :

  1. CH3COCl [ ]H2O CH3COOH
  2. [figure]
  3. CH3CH2OH [(ii) H3O ](i) KMnO4/OH- CH3COOH
  4. CH3CH2CH2OH CrO3-H2SO4 CH3CH2COOH
Ques. 5NEET (UG) 2023

Identify product (A) in the following reaction : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 6NEET (UG) 2023

Complete the following reaction: [figure] [C] is .

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 7NEET (UG) 2023

Identify the major product obtained in the following reaction: [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 8NEET (UG) 2022

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
Ques. 9NEET (UG) 2022

RMgX + CO2 [ether]dry Y H3O+ RCOOH What is Y in the above reaction?

  1. RCOO-Mg+X
  2. R3CO-Mg+X
  3. RCOO-X+
  4. (RCOO)2Mg
Ques. 10NEET (UG) 2022

Match List-I with List-II. Choose the correct answer from the options given below

  1. (a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)
  2. (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)
  3. (a) - (i), (b) - (iii), (c) - (ii), (d) - (iv)
  4. (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)
Ques. 11NEET (UG) 2022

Which one of the following is not formed when acetone reacts with 2-pentanone in the presence of dilute NaOH followed by heating?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

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