Chemical Kinetics

Which plot of k vs 1T is consistent with Arrhenius equation?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

The rate of a reaction quadruples when temperature changes from 27 to 57 . Calculate the energy of activation. Given R = 8.314 J K-1 mol-1, 4 = 0.6021

1. 38.04 kJ/mol
2. 380.4 kJ/mol
3. 3.80 kJ/mol
4. 3804 kJ/mol

Following data is for a reaction between reactants A and B : array|c|c|c| Rate ( mol L-1 s-1) & [A] & [B] \ 2 10-3 & 0.1 M & 0.1 M \ 4 10-3 & 0.2 M & 0.1 M \ 1.6 10-2 & 0.2 M & 0.2 M \ array The order of the reaction with respect to A and B, respectively, are

1. 1, 0
2. 0, 1
3. 1, 2
4. 2, 1

Which of the following plot represents the variation of k versus 1T in accordance with Arrhenius equation?

1. [figure]
2. [figure]
3. [figure]
4. [figure]

Rate constants of a reaction at 500 K and 700 K are 0.04 s-1 and 0.14 s-1, respectively; then, activation energy of the reaction is : (Given: 3.5 = 0.5441, R = 8.31 J K-1 mol-1)

1. 182310 J
2. 18500 J
3. 18219 J
4. 18030 J

For a certain reaction, the rate = k[A]2[B], when the initial concentration of A is tripled keeping concentration of B constant, the initial rate would

1. increase by a factor of six
2. increase by a factor of nine
3. increase by a factor of three
4. decrease by a factor of nine

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. In the light of the above statements, choose the correct answer from the options given below:

1. Both A and R are true but R is NOT the correct explanation of A.
2. A is true but R is false.
3. A is false but R is true.
4. Both A and R are true and R is the correct explanation of A.

The given graph is a representation of kinetics of a reaction [figure] The y and x axes for zero and first order reactions, respectively are

1. zero order (y = concentration and x = time), first order (y = t1/2 and x = concentration)
2. zero order (y = concentration and x = time), first order (y = rate constant and x = concentration)
3. zero order (y = rate and x = concentration), first order (y = t1/2 and x = concentration)
4. zero order (y = rate and x = concentration), first order (y = rate and x = t1/2)

For a first order reaction A Products, initial concentration of A is 0.1 M, which becomes 0.001 M after 5 minutes. Rate constant for the reaction in min-1 is

1. 1.3818
2. 0.9212
3. 0.4606
4. 0.2303

The half life of a first order reaction is 2000 years. If the concentration after 8000 years is 0.02 M, then the initial concentration was :

1. 0.04 M
2. 0.16 M
3. 0.32 M
4. 0.08 M